Catalytic asymmetric deprotonation of phosphine boranes and sulfides as a route to P-stereogenic compounds.

نویسندگان

  • Jonathan J Gammon
  • Steven J Canipa
  • Peter O'Brien
  • Brian Kelly
  • Sven Taylor
چکیده

A comparison between phosphine boranes and sulfides in their catalytic asymmetric deprotonation using organolithiums and sub-stoichiometric amounts of (-)-sparteine has revealed superior catalytic efficiency in the phosphine sulfide deprotonation.

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عنوان ژورنال:
  • Chemical communications

دوره 32  شماره 

صفحات  -

تاریخ انتشار 2008